As an important geochemical observation method, the measurement of gas concentration in fault soil is an important geochemical method to reveal fault properties, fault activities and the adjustment of regional stress field.
Historical moderate-strong earthquake activity is frequent in the southern Liaoning Province, especially in Jinzhou Fault and Haicheng Fault, where many mid-strong earthquakes occurred. So, carrying out continuous observation of soil gas concentration in different sections of Jinzhou Fault and Haicheng Fault in the southern Liaoning Province can provide an important means for analyzing fault activity status and regional stress field adjustment and the characteristics of seismicity.
In this study, we laid out 4 cross-fault measurement lines of soil gas in Jiuzhai-Gaizhoubei section and Gaizhoubei-Anshannan section of Jinzhou Fault and 2 measurement lines on the Haicheng Fault. Based on the results of cross-fault soil gas Rn, CO2 and H2 concentrations measured 7 times from 2018 to 2022 at totally 6 profiles across the Jinzhou and Haicheng faults, and combined with the research results of geological structure, seismic activity, abnormal development of hydrogen in Panjin NO.1 well, GPS observation, b-value variation in the study area and cross-fault leveling in Jinzhou Fault, the paper discusses the concentration intensity and distribution characteristics of fault soil gases of the study area, and the results are as follows:
(1)The concentrations and distribution patterns of soil gas Rn, CO2 and H2 vary greatly in different faults. The concentration of Rn varies from 2.45kBq·m-3 to 140.73kBq·m-3, while that of CO2 is between 0.19%-9.55%, and H2 are from 0.48ppm to 1 527ppm.
In most cases, the distribution of soil gas concentrations on each profile is of single-peak shape and the soil gas concentrations are higher at the outcrops or hanging wall of the fault. The main reason causing this phenomenon is the difference of the fault properties in different sections and the geological features.
(2)The soil gas Rn, CO2 and H2 for the same profile with different periods has a similar consistent variation. The soil gas Rn has a high correlation with CO2, which means that the soil gas Rn is affected by carrier gas of CO2 when migrating and redistributing to the ground along the structural crack of the fault.
(3)The spatial patterns for the mean concentrations of soil gas Rn, CO2 and H2 in the northern area are higher than those in the southern region within the study area, which could be attributed to the characteristics of geologic structure, underground medium structure and vertical crustal deformation, as well as the geological condition of each site.
(4)The temporal variation for the mean concentration values of soil gas Rn, CO2 and H2 of each site has a similar consistent trend, and its dynamic changes show two stages: The mean concentrations of soil gas Rn, CO2 and H2 have a gradual increase trend from May, 2018 to May, 2020, but with a downward recovery trend from October, 2020 to 2022. Combined with seismic activity, abnormal development of hydrogen in Panjin NO.1 well, GPS observation, b-value variation in the study area, cross-fault leveling in Jinzhou Fault and other analysis results, we found that this temporal variation of geochemical characteristics in the study area might be mainly controlled by the properties of fault activity, seismic activity and adjustment of regional stress field. When the fault is under the action of continuous tensile stress, the increase of seismic activity and regional stress field could promote the release of fault soil gas, which might be the reason causing the concentration abnormalities of soil gas.
In a word, it is of great scientific significance to carry out the continuous observation of soil gas on the main active faults in the southern area of Liaoning Province. This research proved that the tectonic geochemical observation with frequent multiple phases not only can provide geochemical data for analyzing the characteristics of gas released on the fault zone in the southern area of Liaoning Province, but also can reflect tectonic activity status and the changes of the regional stress field effectively, which means it might be a good tool for earthquake prediction and monitoring of fault movement.