关键词: LA-ICP-MS, 锆石, U-Pb定年, 地质年代学

Abstract: LA-ICP-MS(laser ablation-inductively coupled-mass spectrometry)has been recently used for rapid, accurate and precise U-Pb geochronology on zircon grains. In this paper, we adopted an Agilent 7900 quadrupole ICP-MS coupled with a Resolution M50-LR 193nm excimer laser system to establish integrated measurement procedures. Before analysis, the system is tuned to achieve sensitivities better than 30000 cps/s for ²³⁸ U with a 40μm spot size, at~3.5J/cm². Detailed parameters for laser system and ICP-MS are presented here. Then, we analyzed five reference zircons(91500, GJ-1, Plesovice, FCT, Penglai)with a wide range in age from~1064 to~4.4Ma. Two standard zircons, 91500 and GJ-1, are employed as external reference standards. Generally, second zircon standard is analyzed in an effort to ensure accuracy and evaluate reproducibility. A typical analysis sequence includes one international glass standard(NIST610), two external reference standards, five grains of unknown zircon with every eight ablations. Laser induced time-dependent elemental fractionation is corrected using the intercept method, whereas instrument drift, mass bias and elemental fractional caused by ionization differences are corrected by external reference standard 91500 or GJ-1. Compared with 91500 and GJ-1, common Pb content of Plesovice, FCT, Penglai can't be ignored. Thus, we did common Pb correction for the above three standard zircons. The performance of the established procedure was assessed by analyzing zircon range in age from~1 064 to~4Ma. The results show that the ages of these five references are consistent with the ages of published studies with accuracy for three international references(91500, GJ-1, Plesovice)better than 3% and two young secondary references(FCT, Penglai)lower than 7% at the 2 sigma level, which indicates that our analytical procedure is reliable. For individual laser analysis, the uncertainties are mainly from three sources:Measurement error of isotope ratio, error of correction factors for instrument drift and element fractionation, and error of recommended age of external references. Compared to three international references, there are three extra uncertainties for young reference zircons, including:1)little radioactive isotopes closing to blank level increase the measurement error of isotope ratio; 2) effect of common lead becomes more significant;3) the nonhomogeneous samples couldn't match references well. Therefore, accuracy and precision of measurement depend on absolute age, content of common lead and matching degree between references and samples. In summary, the accuracy and precision obtained using the technique presented in this study are similar to those of other LA-ICP-MS laboratories.

Key words: LA-ICP-MS, zircon, U-Pb dating, geochronology